Cu-catalyzed oxidative Povarov reactions between N-alkyl N-methylanilines and saturated oxa- and thiacycles.

نویسندگان

  • Rahul Kisan Kawade
  • Deepak B Huple
  • Rong-Jing Lin
  • Rai-Shung Liu
چکیده

Cu-catalyzed oxidative Povarov reactions between N,N-dialkylanilines and saturated oxa- or thiacycles with tert-butyl hydroperoxide (TBHP) are described; notably, the reactions use neither [4π] nor [2π]-motifs as the initial reagents. The use of cheap alkane-based substances as building units is of mechanistic and practical interest as two inert sp(3) C-H bonds are activated.

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عنوان ژورنال:
  • Chemical communications

دوره 51 30  شماره 

صفحات  -

تاریخ انتشار 2015